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Complex Formation Between Silver and Thiocyanate Ions in Aqueous Solutions.

UCRLTRANS11006

Publication Date	1955
Personal Author	Leden, I.; Nilsson, R.
Page Count	27
Abstract	Studies were made on the type and strength of the silver thiocyanate complex in aqueous solutions with thiocyanate ion concentrations between 10 exp -6 and 4 m. Measurements were made of the solubility of silver thiocyanate AgSCN and silver sodium dithiocyanate NaAg(SCN) sub 2 (H sub 2 O) sub 2 in sodium thiocyanate solutions whose ion strength was maintained constant through the addition of sodium perchlorate. A few potentiometric measurements were made in unsaturated silver thiocyanate. Mononuclear complexes Ag(SCN)/sub n/1-n with n = 1, 2, 3 and 4 were found. The multilinear complexes are apparently Ag/sub m/(SCN)/sub 2m+2//sup -(m+2)/, where m can assume all the whole number values, including very large ones. All measurements were carried out at 25 exp 0 C. (ERA citation 01:013806)
Keywords	Silver complexes Sodium complexes Thiocyanates Aqueous solutions Chemical reactions Potentiometry Solubility ERDA/400201 Translations West Germany
Source Agency	ERDA Translation
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Document Type	Technical Report
NTIS Issue Number	197621

Complex Formation Between Silver and Thiocyanate Ions in Aqueous Solutions.

Complex Formation Between Silver and Thiocyanate Ions in Aqueous Solutions.
UCRLTRANS11006

Publication Date	1955
Personal Author	Leden, I.; Nilsson, R.
Page Count	27
Abstract	Studies were made on the type and strength of the silver thiocyanate complex in aqueous solutions with thiocyanate ion concentrations between 10 exp -6 and 4 m. Measurements were made of the solubility of silver thiocyanate AgSCN and silver sodium dithiocyanate NaAg(SCN) sub 2 (H sub 2 O) sub 2 in sodium thiocyanate solutions whose ion strength was maintained constant through the addition of sodium perchlorate. A few potentiometric measurements were made in unsaturated silver thiocyanate. Mononuclear complexes Ag(SCN)/sub n/1-n with n = 1, 2, 3 and 4 were found. The multilinear complexes are apparently Ag/sub m/(SCN)/sub 2m+2//sup -(m+2)/, where m can assume all the whole number values, including very large ones. All measurements were carried out at 25 exp 0 C. (ERA citation 01:013806)
Keywords	Silver complexes Sodium complexes Thiocyanates Aqueous solutions Chemical reactions Potentiometry Solubility ERDA/400201 Translations West Germany
Source Agency	ERDA Translation
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Document Type	Technical Report
NTIS Issue Number	197621