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Radiation Chemistry and Photochemistry of Periodate Ion in Aqueous Solution.

PB94147428

Publication Date	1989
Personal Author	Latif, R.
Page Count	141
Abstract	The radiolytic and photolytic decomposition of IO(4) ion in aqueous solution at natural pH was studied. The radiation chemical yield (G-value) and the (phi-value) for the disappearance of IO(4) ion and for the formation of IO(3) ion and O2, were determined in argon saturated, N2O saturated solution and in the presence of formate ion. The theoretically calculated G-values on the basis of the proposed mechanism for the radiolytic decomposition of IO4 ion are in good agreement with the experimentally determined values.
Keywords	Radiation chemistry Photochemistry Periodates Aqueous solutions Decomposition reactions Photolysis Radiolysis Steady state Radicals Excited states Quantum efficiency Chemical reaction yield Chemical reaction kinetics Foreign technology Periodate ions
Source Agency	Foreign Technology-Pinstech, Islamabad, Pakistan
NTIS Subject Category	99E - Photochemistry and Radiation Chemistry
Corporate Authors	Quaid-i-Azam Univ., Islamabad (Pakistan). Dept. of Chemistry.
Document Type	Thesis
Title Note	Master's thesis.
NTIS Issue Number	199411

Radiation Chemistry and Photochemistry of Periodate Ion in Aqueous Solution.

Radiation Chemistry and Photochemistry of Periodate Ion in Aqueous Solution.
PB94147428

Publication Date	1989
Personal Author	Latif, R.
Page Count	141
Abstract	The radiolytic and photolytic decomposition of IO(4) ion in aqueous solution at natural pH was studied. The radiation chemical yield (G-value) and the (phi-value) for the disappearance of IO(4) ion and for the formation of IO(3) ion and O2, were determined in argon saturated, N2O saturated solution and in the presence of formate ion. The theoretically calculated G-values on the basis of the proposed mechanism for the radiolytic decomposition of IO4 ion are in good agreement with the experimentally determined values.
Keywords	Radiation chemistry Photochemistry Periodates Aqueous solutions Decomposition reactions Photolysis Radiolysis Steady state Radicals Excited states Quantum efficiency Chemical reaction yield Chemical reaction kinetics Foreign technology Periodate ions
Source Agency	Foreign Technology-Pinstech, Islamabad, Pakistan
NTIS Subject Category	99E - Photochemistry and Radiation Chemistry
Corporate Authors	Quaid-i-Azam Univ., Islamabad (Pakistan). Dept. of Chemistry.
Document Type	Thesis
Title Note	Master's thesis.
NTIS Issue Number	199411