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Trinitropyridin und Verwandte Stoffe: Synthese und Charakterisierung (Trinitropyridine and Analogous Compounds: Synthesis and Characterization) (Trinitropyridine et Composes Analogues: Synthese et Caracterisation),


PB89128110

Publication Date 1988
Personal Author Licht, H. H.; Wanders, B.; Ritter, H.
Page Count 26
Abstract A detailed study of the formation of trinitropyridine-1-oxide (TNPyOx) from dinitroethanol pointed towards a path to the as yet unknown trinitropyridine (TNPy). This made nitropyridines accessible which can not be obtained by direct nitration. The new substances could be characterized by analytical methods and their spectral data (IR, UV and NMR). The synthesis evolved to such a point that sufficient substance amounts became available for a determination of the most important physical, thermal and explosive properties. Calculations of their maximal detonation rates (TNPy : 7,880; TNPyOx : 8,450) and their Gurney constants (TNPy : 2.64; TNPyOx : 2.79) based on theory make it possible to predict that here are two new explosives with a power exceeding that of TNT or Composition B.
Keywords
  • Spectrum analysis
  • Explosives
  • Nitro compounds
  • Synthesis
  • Graphs(Charts)
  • Detonators
  • Pyridines
  • Chemical analysis
  • Infrared spectroscopy
  • Nuclear magnetic resonance
  • Foreign technology
Source Agency
  • Center De Documentation De L'armenent France
NTIS Subject Category
  • 79A - Ammunition, Explosives, & Pyrotechnics
  • 99D - Basic & Synthetic Chemistry
Corporate Authors Institut Franco-Allemand de Recherches, Saint-Louis (France).; Direction des Recherches, Etudes et Techniques, Paris (France). Centre de
Supplemental Notes Text in German; summary in French and English. Sponsored by Direction des Recherches, Etudes et Techniques, Paris (France). Centre de Documentation de l'Armement.
Document Type Technical Report
NTIS Issue Number 198905
Trinitropyridin und Verwandte Stoffe: Synthese und Charakterisierung (Trinitropyridine and Analogous Compounds: Synthesis and Characterization) (Trinitropyridine et Composes Analogues: Synthese et Caracterisation),
Trinitropyridin und Verwandte Stoffe: Synthese und Charakterisierung (Trinitropyridine and Analogous Compounds: Synthesis and Characterization) (Trinitropyridine et Composes Analogues: Synthese et Caracterisation),
PB89128110

  • Spectrum analysis
  • Explosives
  • Nitro compounds
  • Synthesis
  • Graphs(Charts)
  • Detonators
  • Pyridines
  • Chemical analysis
  • Infrared spectroscopy
  • Nuclear magnetic resonance
  • Foreign technology
  • Center De Documentation De L'armenent France
  • 79A - Ammunition, Explosives, & Pyrotechnics
  • 99D - Basic & Synthetic Chemistry
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