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Mechanism of Lubrication by Tricresylphosphate (Tcp).


N8318863

Publication Date 1983
Personal Author Faut, O. D.; Wheeler, D. R.
Page Count 14
Abstract A pin-on-disk tribometer equipped with an induction heater was used to study the coefficient of friction as a function of temperature for tricresylphosphate (TCP) on continuous vacuum melted (CVM) M-50 tool steel when the TCP was present in a liquid reservoir (bulk lubrication), and when it was applied as a liquid layer directly to the disk (limited lubrication). Under limited lubrication conditions, experiments were performed in dry ( 100 ppm H2O) air, dry ( 20 ppm H2O) nitrogen, dry nitrogen with the disks heated to 700 C then cooled to room temperature before the TCP was applied and the measurements made (preheated disks), and moist nitrogen using preheated disks. When the coefficient of friction was plotted as a function of the disk temperature, the friction decreased at a characteristic temperature, T sub r whose observed values were 265 C for bulk lubrication conditions in dry air, 225 C for limited lubrication conditions in dry air, and 215 C for limited lubrication conditions in dry nitrogen. No decrease in friction was observed with preheated disks; instead a sharp failure temperature was observed at 218 C, which was taken as the temperature about which the behavior of TCP should be judged, X-ray photoelectron spectroscopy confirmed the presence of phosphate on the surface of the iron pins used in the tribometer under TCP lubrication. Depth profile studies support the idea that a chemical reaction occurs between the TCP and the metal surface at T sub r.
Keywords
  • Chemical reactions
  • Coefficient of friction
  • Lubricants
  • Metal surfaces
  • Phosphates
  • Temperature measurement
  • Air
  • Induction heating
  • Moisture content
  • Nitrogen
  • Photoelectron spectroscopy
  • Tribology
  • Phosphoric acid/(tricresyl-ester)
Source Agency
  • National Aeronautics and Space Administration
NTIS Subject Category
  • 71K - Lubricants & Hydraulic Fluids
  • 99F - Physical & Theoretical Chemistry
Corporate Authors National Aeronautics and Space Administration, Cleveland, OH. Lewis Research Center.
Supplemental Notes Presented at the Asle Lubrication Conf., Washington, D.C., 5-7 Oct. 1982.
Document Type Technical Report
NTIS Issue Number 198314
Mechanism of Lubrication by Tricresylphosphate (Tcp).
Mechanism of Lubrication by Tricresylphosphate (Tcp).
N8318863

  • Chemical reactions
  • Coefficient of friction
  • Lubricants
  • Metal surfaces
  • Phosphates
  • Temperature measurement
  • Air
  • Induction heating
  • Moisture content
  • Nitrogen
  • Photoelectron spectroscopy
  • Tribology
  • Phosphoric acid/(tricresyl-ester)
  • National Aeronautics and Space Administration
  • 71K - Lubricants & Hydraulic Fluids
  • 99F - Physical & Theoretical Chemistry
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