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Electrochemistry in nonaqueous solvents. Foreign trip report, August 27-September 10, 1988.

DE90012357

Publication Date	1988
Personal Author	Payne, G. F.
Page Count	10
Abstract	The traveler attended the XXVI International Conference on Coordination Chemistry and presented some work entitled ''An Investigation of the Perchlorate Complexation of Europium(III) in Benzonitrile and Dimethylsulphoxide Using an Ion Exchange Technique.'' Papers of particular interest concerned electrochemistry in nonaqueous solvents (in particular, using electrodes of submicron dimensions that could be applicable to the later actinides); Raman spectroscopy as applied to coordination chemistry, and solution chemistry in nonaqueous solvents with emphasis on identifying the species in solution. The traveler also attended the XIII International Conference on Organometallic Chemistry in Turin, Italy and presented work entitled ''Synthesis and Characterization of Some Divalent and Trivalent Samarium Organometallic Complexes.'' Papers of particular interest were given in a complete session on organometallic chemistry of the f-elements. Other papers useful to our work concerned d-transition metals where phosphine, arsine, and stibine ligands were used (in order to compare and contrast the behavior with the work we have done on this type of ligand with europium) and phosphide and sulphur bridged type species applicable to both d-transition and f-transition metals.
Keywords	Organometallic Compounds Electrochemistry Electrodes Nonaqueous Solvents Portugal Raman Spectroscopy Transition Elements Travel EDB/400400 Meetings
Source Agency	Technical Information Center Oak Ridge Tennessee
NTIS Subject Category	99F - Physical & Theoretical Chemistry
Corporate Authors	Oak Ridge National Lab., TN.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	199023
Contract Number	AC05-84OR21400

Electrochemistry in nonaqueous solvents. Foreign trip report, August 27-September 10, 1988.

Electrochemistry in nonaqueous solvents. Foreign trip report, August 27-September 10, 1988.
DE90012357

Publication Date	1988
Personal Author	Payne, G. F.
Page Count	10
Abstract	The traveler attended the XXVI International Conference on Coordination Chemistry and presented some work entitled ''An Investigation of the Perchlorate Complexation of Europium(III) in Benzonitrile and Dimethylsulphoxide Using an Ion Exchange Technique.'' Papers of particular interest concerned electrochemistry in nonaqueous solvents (in particular, using electrodes of submicron dimensions that could be applicable to the later actinides); Raman spectroscopy as applied to coordination chemistry, and solution chemistry in nonaqueous solvents with emphasis on identifying the species in solution. The traveler also attended the XIII International Conference on Organometallic Chemistry in Turin, Italy and presented work entitled ''Synthesis and Characterization of Some Divalent and Trivalent Samarium Organometallic Complexes.'' Papers of particular interest were given in a complete session on organometallic chemistry of the f-elements. Other papers useful to our work concerned d-transition metals where phosphine, arsine, and stibine ligands were used (in order to compare and contrast the behavior with the work we have done on this type of ligand with europium) and phosphide and sulphur bridged type species applicable to both d-transition and f-transition metals.
Keywords	Organometallic Compounds Electrochemistry Electrodes Nonaqueous Solvents Portugal Raman Spectroscopy Transition Elements Travel EDB/400400 Meetings
Source Agency	Technical Information Center Oak Ridge Tennessee
NTIS Subject Category	99F - Physical & Theoretical Chemistry
Corporate Authors	Oak Ridge National Lab., TN.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	199023
Contract Number	AC05-84OR21400