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CO2 Separation Using Thermally Optimized Membranes: A Comprehensive Project Report (2000 - 2007).

DE2009948581

Publication Date	2008
Page Count	105
Abstract	This is a complete (Fiscal Years 2000-2006) collection of the Idaho National Laboratory's (INL) research and development contributions to the project, CO2 Separation Using Thermally Optimized Membranes. The INL scientific contribution to the project has varied due to the fluctuations in funding from year to year. The focus of the project was polybenzimidazole (PBI) membranes and developing PBI compounds (both substitution and blends) that provide good film formation and gas separation membranes. The underlying problem with PBI is its poor solubility in common solvents. Typically, PBI is dissolved in aggressive solvents, like N,N-dimethylacetamide (DMAc) and N methylpyrrolidone (NMP). The INL FY-03 research was directed toward making soluble N-substituted PBI polymers, where INL was very successful. Many different types of modified PBI polymers were synthesized; however, film formation proved to be a big problem with both unsubstituted and N-substituted PBIs. Therefore, INL researchers directed their attention to using plasticizers or additives to make the membranes more stable and workable. During the course of these studies, other high-performance polymers (like polyamides and polyimides) were found to be better materials, which could be used either by themselves or blends with PBI. These alternative high-performance polymers provided the best pathway forward for soluble high-temperature polymers with good stable film formation properties. At present, the VTEC polyimides (product of RBI, Inc.) are the best film formers that exhibit high-temperature resistance. INL's gas testing results show VTEC polyimides have very good gas selectivities for both H2/CO2 and CO2/CH4.
Keywords	Carbon dioxide Separation processes Membranes Membrane transport Solubility Solvents Polymers Benzimidazoles Performance evaluation Testing Research and development
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Idaho National Laboratory, Idaho Falls, ID.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200921
Contract Number	DE-AC07-05ID14517

CO2 Separation Using Thermally Optimized Membranes: A Comprehensive Project Report (2000 - 2007).

CO2 Separation Using Thermally Optimized Membranes: A Comprehensive Project Report (2000 - 2007).
DE2009948581

Publication Date	2008
Page Count	105
Abstract	This is a complete (Fiscal Years 2000-2006) collection of the Idaho National Laboratory's (INL) research and development contributions to the project, CO2 Separation Using Thermally Optimized Membranes. The INL scientific contribution to the project has varied due to the fluctuations in funding from year to year. The focus of the project was polybenzimidazole (PBI) membranes and developing PBI compounds (both substitution and blends) that provide good film formation and gas separation membranes. The underlying problem with PBI is its poor solubility in common solvents. Typically, PBI is dissolved in aggressive solvents, like N,N-dimethylacetamide (DMAc) and N methylpyrrolidone (NMP). The INL FY-03 research was directed toward making soluble N-substituted PBI polymers, where INL was very successful. Many different types of modified PBI polymers were synthesized; however, film formation proved to be a big problem with both unsubstituted and N-substituted PBIs. Therefore, INL researchers directed their attention to using plasticizers or additives to make the membranes more stable and workable. During the course of these studies, other high-performance polymers (like polyamides and polyimides) were found to be better materials, which could be used either by themselves or blends with PBI. These alternative high-performance polymers provided the best pathway forward for soluble high-temperature polymers with good stable film formation properties. At present, the VTEC polyimides (product of RBI, Inc.) are the best film formers that exhibit high-temperature resistance. INL's gas testing results show VTEC polyimides have very good gas selectivities for both H2/CO2 and CO2/CH4.
Keywords	Carbon dioxide Separation processes Membranes Membrane transport Solubility Solvents Polymers Benzimidazoles Performance evaluation Testing Research and development
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Idaho National Laboratory, Idaho Falls, ID.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200921
Contract Number	DE-AC07-05ID14517