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Adsorption of the Lighter Homologs of Element 104 and Element 105 on DGA Resin from Various Mineral Acids.


DE2009945879

Publication Date 2009
Personal Author Bennett, M. E.; Sudowe, R.
Page Count 12
Abstract The goal of studying transactinide elements is to further understand the fundamental principles that govern the periodic table. The current periodic table arrangement allows for the prediction of the chemical behavior of elements. The correct position of a transactinide element can be assessed by investigating its chemical behavior and comparing it to that of the homologs and pseudo-homologs of a transactinide element. Homologs of a transactinide element are the elements in the same group of the periodic table as the transactinide. A pseudo-homolog of a transactinide element is an element with a similar main oxidation state and similar ionic radius to the transactinide element. For example, the homologs of rutherfordium, Rf, are titanium, zirconium and hafnium (Ti, Zr and Hf); the pseudo homologs of Rf are thorium, Th, and plutonium, Pu. Understanding the chemical behavior of a transactinide element compared to its homologs and pseudo-homologs also allows for the assessment of the role of relativistic effects. Relativistic effects occur when the velocity of the s orbital electrons closest to the nucleus approaches the speed of light. These electrons approach the speed of light because they have no orbital momentum.
Keywords
  • Radiation chemistry
  • Radiochemistry
  • Nuclear chemistry
  • Actinides
  • Adsorption
  • Ammonium hydroxides
  • Angular momentum
  • Aqua regia
  • Chemical properties
  • Chemical state
  • Chemistry
  • Cold fusion
  • Copper
  • Dubnium
  • Excitation
  • Inorganic acids
  • Mass number
  • Nuclear reactions
  • Nuclei
  • Quantum numbers
  • Radioisotopes
  • Resins
  • Transactinide elements
  • Valence
Source Agency
  • Technical Information Center Oak Ridge Tennessee
Corporate Authors Lawrence Livermore National Lab., CA.; Department of Energy, Washington, DC.
Supplemental Notes Sponsored by Department of Energy, Washington, DC.
Document Type Technical Report
NTIS Issue Number 200911
Adsorption of the Lighter Homologs of Element 104 and Element 105 on DGA Resin from Various Mineral Acids.
Adsorption of the Lighter Homologs of Element 104 and Element 105 on DGA Resin from Various Mineral Acids.
DE2009945879

  • Radiation chemistry
  • Radiochemistry
  • Nuclear chemistry
  • Actinides
  • Adsorption
  • Ammonium hydroxides
  • Angular momentum
  • Aqua regia
  • Chemical properties
  • Chemical state
  • Chemistry
  • Cold fusion
  • Copper
  • Dubnium
  • Excitation
  • Inorganic acids
  • Mass number
  • Nuclear reactions
  • Nuclei
  • Quantum numbers
  • Radioisotopes
  • Resins
  • Transactinide elements
  • Valence
  • Technical Information Center Oak Ridge Tennessee
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