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Demonstration and System Analysis of High Temperature Steam Electrolysis for Large-Scale Hydrogen Production Using SOFCs. 8th European SOFC Forum (Preprint).


DE2008935459

Publication Date 2008
Personal Author McKellar, M. G.; O'Brien, J. E.; Stoots, C. M.; Herring, J. S.
Page Count 14
Abstract At the Idaho National Engineering Laboratory, an integrated laboratory scale (ILS), 15 kW high-temperature electrolysis (HTE) facility has been developed under the U.S. Department of Energy Nuclear Hydrogen Initiative. Initial operation of this facility resulted in over 400 hours of operation with an average hydrogen production rate of approximately 0.9 Nm3/hr. The integrated laboratory scale facility is designed to address larger-scale issues such as thermal management (feed-stock heating, high-temperature gas handling), multiple-stack hot-zone design, multiple-stack electrical configurations, and other integral issues. Additionally, a reference process model of a commercial-scale high-temperature electrolysis plant for hydrogen production has been developed. The reference plant design is driven by a 600 megawatt thermal high-temperature helium-cooled reactor coupled to a direct Brayton power cycle. The electrolysis unit used to produce hydrogen consists of 4.01OE106 cells with a per-cell active area of 225 cm2. A nominal cell area-specific resistance, ASR, value of 0.4 Ohmcm2 with a current density of 0.25 A/cm2 was used, and isothermal boundary conditions were assumed. The overall system thermal-to-hydrogen production efficiency (based on the low heating value of the produced hydrogen) is 47.1% at a hydrogen production rate of 2.36 kg/s with the high-temperature helium-cooled reactor concept.
Keywords
  • Hydrogen production
  • Electrolysis
  • Solid oxide fuel cells
  • Boundary conditions
  • Current density
  • Design
  • Steam
  • Economics
  • Efficiency
  • Heating
  • Helium cooled reactors
  • High temperature electrolysis (HTE)
Source Agency
  • Technical Information Center Oak Ridge Tennessee
Corporate Authors Idaho National Laboratory, Idaho Falls, ID.; Department of Energy, Washington, DC.
Supplemental Notes Sponsored by Department of Energy, Washington, DC.
Document Type Technical Report
NTIS Issue Number 200901
Demonstration and System Analysis of High Temperature Steam Electrolysis for Large-Scale Hydrogen Production Using SOFCs. 8th European SOFC Forum (Preprint).
Demonstration and System Analysis of High Temperature Steam Electrolysis for Large-Scale Hydrogen Production Using SOFCs. 8th European SOFC Forum (Preprint).
DE2008935459

  • Hydrogen production
  • Electrolysis
  • Solid oxide fuel cells
  • Boundary conditions
  • Current density
  • Design
  • Steam
  • Economics
  • Efficiency
  • Heating
  • Helium cooled reactors
  • High temperature electrolysis (HTE)
  • Technical Information Center Oak Ridge Tennessee
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