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Chemistry at Extreme Conditions.

DE200515013465

Publication Date	2002
Personal Author	Zaug, J. M.; Fried, L. E.; Abramson, E. H.; Hansen, D. W.; Crowhurst, J. C.; Howard, W. M.
Page Count	10
Abstract	We present equation of state results from impulsively stimulated light scattering (ISLS) experiments conducted in diamond anvil cells on pure supercritical fluids. We have made measurements on fluid H2O (water), and CH(sub 3)OH (methanol). Sound speeds measured through ISLS have allowed us to refine existing potential models used in the exponential-6 (EXP-6) detonation product library (Fried, L. E., and Howard, W. M., J. Chem. Phys. 109 (17): 7338-7348 (1998).). The refined models allow us to more accurately assess the chemical composition at the Chapman-Jouget (C-J) state of common energetic materials. We predict that water is present in appreciable quantities at the C-J state of energetic materials HMX, RDX, and nitro methane.
Keywords	Chemistry Equations of state High pressure High temperature Quantitative analysis Light scattering Water Methanol Extreme conditions
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Lawrence Livermore National Lab., CA.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200519

Chemistry at Extreme Conditions.

Chemistry at Extreme Conditions.
DE200515013465

Publication Date	2002
Personal Author	Zaug, J. M.; Fried, L. E.; Abramson, E. H.; Hansen, D. W.; Crowhurst, J. C.; Howard, W. M.
Page Count	10
Abstract	We present equation of state results from impulsively stimulated light scattering (ISLS) experiments conducted in diamond anvil cells on pure supercritical fluids. We have made measurements on fluid H2O (water), and CH(sub 3)OH (methanol). Sound speeds measured through ISLS have allowed us to refine existing potential models used in the exponential-6 (EXP-6) detonation product library (Fried, L. E., and Howard, W. M., J. Chem. Phys. 109 (17): 7338-7348 (1998).). The refined models allow us to more accurately assess the chemical composition at the Chapman-Jouget (C-J) state of common energetic materials. We predict that water is present in appreciable quantities at the C-J state of energetic materials HMX, RDX, and nitro methane.
Keywords	Chemistry Equations of state High pressure High temperature Quantitative analysis Light scattering Water Methanol Extreme conditions
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Lawrence Livermore National Lab., CA.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200519