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Calcite Precipitation and Trace Metal Partitioning in Groundwater and the Vadose Zone: Remediation of Strontium-90 and Other Divalent Metals and Radionuclides in Arid Western Environments. 2001 Project Summary.

DE2004833668

Publication Date	2001
Personal Author	Smith, R. W.; Colwell, F. R. S.; Ingram, J. C.
Page Count	8
Abstract	Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. Demonstrating in situ immobilization of these contaminants in vadose zones or groundwater plumes is a cost-effective remediation strategy. However, the implementation of in situ remediation requires definition of the mechanism that controls sequestration of the contaminants. One such mechanism for metals and radionuclides is co-precipitation of these elements in authigenic calcite and calcite overgrowths. Calcite, a common mineral in many aquifers and vadose zones in the arid western U.S., can incorporate divalent metals such as strontium, cadmium, lead, and cobalt into its crystal structure by the formation of solid solutions. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution, solid solution properties of the trace metal in calcite, and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning and how this may occur in aquifers and vadose environments is lacking. The focus of the research proposed here is to investigate the facilitated partitioning of metal and radionuclides by their coprecipitation with calcium carbonate. Our specific research objectives include: (1) Elucidating the mechanisms and rates of microbially facilitated calcite precipitation and divalent cation adsorption/co-precipitation occurring in a natural aquifer as a result of the introduction of urea. (2) Assessing the effects of spatial variability in aquifer host rock and the associated hydro/biogeochemical processes on calcite precipitation rates and mineral phases within an aquifer.
Keywords	Aquifers Strontium 90 Coprecipitation Bioremediation Microorganisms Groundwater Radioisotopes Spatial distribution Urea Precipitation Crystal structure Cobalt Plumes Cations
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Idaho National Engineering and Environmental Lab., Idaho Falls.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200512

Calcite Precipitation and Trace Metal Partitioning in Groundwater and the Vadose Zone: Remediation of Strontium-90 and Other Divalent Metals and Radionuclides in Arid Western Environments. 2001 Project Summary.

Calcite Precipitation and Trace Metal Partitioning in Groundwater and the Vadose Zone: Remediation of Strontium-90 and Other Divalent Metals and Radionuclides in Arid Western Environments. 2001 Project Summary.
DE2004833668

Publication Date	2001
Personal Author	Smith, R. W.; Colwell, F. R. S.; Ingram, J. C.
Page Count	8
Abstract	Radionuclide and metal contaminants are present in the vadose zone and groundwater throughout the U.S. Department of Energy (DOE) weapons complex. Demonstrating in situ immobilization of these contaminants in vadose zones or groundwater plumes is a cost-effective remediation strategy. However, the implementation of in situ remediation requires definition of the mechanism that controls sequestration of the contaminants. One such mechanism for metals and radionuclides is co-precipitation of these elements in authigenic calcite and calcite overgrowths. Calcite, a common mineral in many aquifers and vadose zones in the arid western U.S., can incorporate divalent metals such as strontium, cadmium, lead, and cobalt into its crystal structure by the formation of solid solutions. The rate at which trace metals are incorporated into calcite is a function of calcite precipitation kinetics, adsorption interactions between the calcite surface and the trace metal in solution, solid solution properties of the trace metal in calcite, and also the surfaces upon which the calcite is precipitating. A fundamental understanding of the coupling of calcite precipitation and trace metal partitioning and how this may occur in aquifers and vadose environments is lacking. The focus of the research proposed here is to investigate the facilitated partitioning of metal and radionuclides by their coprecipitation with calcium carbonate. Our specific research objectives include: (1) Elucidating the mechanisms and rates of microbially facilitated calcite precipitation and divalent cation adsorption/co-precipitation occurring in a natural aquifer as a result of the introduction of urea. (2) Assessing the effects of spatial variability in aquifer host rock and the associated hydro/biogeochemical processes on calcite precipitation rates and mineral phases within an aquifer.
Keywords	Aquifers Strontium 90 Coprecipitation Bioremediation Microorganisms Groundwater Radioisotopes Spatial distribution Urea Precipitation Crystal structure Cobalt Plumes Cations
Source Agency	Technical Information Center Oak Ridge Tennessee
Corporate Authors	Idaho National Engineering and Environmental Lab., Idaho Falls.; Department of Energy, Washington, DC.
Supplemental Notes	Sponsored by Department of Energy, Washington, DC.
Document Type	Technical Report
NTIS Issue Number	200512