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Annual Report. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste.


DE2004829897

Publication Date 2002
Personal Author Macdonald, D. D.; Liu, S.; Sikora, E.; Liu, J.
Page Count 66
Abstract The current report summarizes work performed on the project over the past calendar year (2001). The work concentrated on four areas: the fracture of AISI 4340 steel simulating weld heat-affected zones in DOE liquid waste storage tanks, investigation of the passive state on nickel, which is commonly used for containing highly alkaline solutions, development of a new theory for the transient growth of passive films on metals in contact with aqueous solutions, and exploration of the passive state on iron, because it is passivity that allows iron-based alloys to be used to contain DOE's liquid waste. Fracture of AISI 4340 steel in concentrated sodium hydroxide solution has been monitored by measuring the coupling current that flows between the crack and the external surfaces.
Keywords
  • Electrochemical corrosion
  • Spectroscopy
  • Liquid wastes
  • Storage tanks
  • High-level radioactive wastes
  • Aqueous solutions
  • Crack propagation
  • Dimensions
  • Grain boundaries
  • Measuring methods
  • Metals
  • Alloys
  • Monitoring
  • Transients
  • Steels
  • Cathodes
  • Hydrogen embrittlement
  • Amplitudes
  • Fractures
Source Agency
  • Technical Information Center Oak Ridge Tennessee
Corporate Authors Pennsylvania State Univ., University Park. Center for Electrochemical Science and Technology.; Department of Energy, Washington, DC.
Supplemental Notes Sponsored by Department of Energy, Washington, DC.
Document Type Technical Report
NTIS Issue Number 200512
Annual Report. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste.
Annual Report. Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste.
DE2004829897

  • Electrochemical corrosion
  • Spectroscopy
  • Liquid wastes
  • Storage tanks
  • High-level radioactive wastes
  • Aqueous solutions
  • Crack propagation
  • Dimensions
  • Grain boundaries
  • Measuring methods
  • Metals
  • Alloys
  • Monitoring
  • Transients
  • Steels
  • Cathodes
  • Hydrogen embrittlement
  • Amplitudes
  • Fractures
  • Technical Information Center Oak Ridge Tennessee
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