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Kinetic analysis of high nitrogen energetic materials using multivariate non-linear regression.

DE2001783687

Publication Date	2001
Personal Author	Campbell, M. S.
Page Count	7
Abstract	New high-nitrogen energetic materials were synthesized by Hiskey and Naud. J. Opfermann reported a new tool for finding the probable model of the complex reactions using multivariate non-linear regression analysis of DSC and TGA data from several measurements run at different heating rates. This study is to take the kinetic parameters from the different steps and discover which reaction step is responsible for the runaway reaction by comparing predicted results from the Frank-Kamenetsckii equation with the critical temperature found experimentally using the modified Henkin test.
Keywords	Chemical reaction kinetics Regression analysis Nonlinear problems Kinetics Nitro compounds Chemical explosives Multivariate analysis
Source Agency	Technical Information Center Oak Ridge Tennessee
NTIS Subject Category	99F - Physical & Theoretical Chemistry
Corporate Authors	Los Alamos National Lab., NM.; Department of Energy, Washington, DC.
Document Type	Conference Proceedings
NTIS Issue Number	200208
Contract Number	W-7405-ENG-36

Kinetic analysis of high nitrogen energetic materials using multivariate non-linear regression.

Kinetic analysis of high nitrogen energetic materials using multivariate non-linear regression.
DE2001783687

Publication Date	2001
Personal Author	Campbell, M. S.
Page Count	7
Abstract	New high-nitrogen energetic materials were synthesized by Hiskey and Naud. J. Opfermann reported a new tool for finding the probable model of the complex reactions using multivariate non-linear regression analysis of DSC and TGA data from several measurements run at different heating rates. This study is to take the kinetic parameters from the different steps and discover which reaction step is responsible for the runaway reaction by comparing predicted results from the Frank-Kamenetsckii equation with the critical temperature found experimentally using the modified Henkin test.
Keywords	Chemical reaction kinetics Regression analysis Nonlinear problems Kinetics Nitro compounds Chemical explosives Multivariate analysis
Source Agency	Technical Information Center Oak Ridge Tennessee
NTIS Subject Category	99F - Physical & Theoretical Chemistry
Corporate Authors	Los Alamos National Lab., NM.; Department of Energy, Washington, DC.
Document Type	Conference Proceedings
NTIS Issue Number	200208
Contract Number	W-7405-ENG-36