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Convenient Synthesis of Diaminoglyoxime and Diaminofurazan: Useful Precursors for the Synthesis of High Density Energetic Materials.


ADA292429

Publication Date 1995
Personal Author Gunasekaran, A.; Jayachandran, T.; Boyer, J. H.; Trudell, M. L.
Page Count 10
Abstract The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueous sodium hydroxide was found to be a safe and inexpensive method for the preparation of multigram quantities of diaminoglyoxime (5). Potassium hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 has facilitated the synthesis of new energetic furazan derivative MNOTO (B). jg.
Keywords
  • High density
  • Energetic properties
  • Oximes
  • Solutions(Mixtures)
  • Synthesis
  • Materials
  • Composite materials
  • Carbon
  • Nitrogen
  • Hydrogen
  • Oxygen
  • Amines
  • Purity
  • Chlorides
  • Methane
  • Hydroxyl radicals
  • Potassium compounds
  • Nitramines
  • Sodium hydroxide
  • Oxadiazoles
  • Glyoximes
  • Diaminofurazan
  • Diaminoglyoxime
  • Hydrochloride
  • Mnoto(Methanedinitr amino-oxdiazol- triazolo-oxadiazolium)
  • Furazan
Source Agency
  • Non Paid ADAS
NTIS Subject Category
  • 79A - Ammunition, Explosives, & Pyrotechnics
  • 99D - Basic & Synthetic Chemistry
Corporate Authors New Orleans Univ., LA. Dept. of Chemistry.
Document Type Technical Report
Title Note Technical rept.
NTIS Issue Number 199521
Contract Number
  • N00014-90-J-1661
Convenient Synthesis of Diaminoglyoxime and Diaminofurazan: Useful Precursors for the Synthesis of High Density Energetic Materials.
Convenient Synthesis of Diaminoglyoxime and Diaminofurazan: Useful Precursors for the Synthesis of High Density Energetic Materials.
ADA292429

  • High density
  • Energetic properties
  • Oximes
  • Solutions(Mixtures)
  • Synthesis
  • Materials
  • Composite materials
  • Carbon
  • Nitrogen
  • Hydrogen
  • Oxygen
  • Amines
  • Purity
  • Chlorides
  • Methane
  • Hydroxyl radicals
  • Potassium compounds
  • Nitramines
  • Sodium hydroxide
  • Oxadiazoles
  • Glyoximes
  • Diaminofurazan
  • Diaminoglyoxime
  • Hydrochloride
  • Mnoto(Methanedinitr amino-oxdiazol- triazolo-oxadiazolium)
  • Furazan
  • Non Paid ADAS
  • 79A - Ammunition, Explosives, & Pyrotechnics
  • 99D - Basic & Synthetic Chemistry
  • N00014-90-J-1661
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