National Technical Reports Library

The National Technical Information Service acquires, indexes, abstracts, and archives the largest collection of U.S. government-sponsored technical reports in existence. The NTRL offers online, free and open access to these authenticated government technical reports. Technical reports and documents in its repository may be available online for free either from the issuing federal agency, the U.S. Government Publishing Office’s Federal Digital System website, or through search engines.

Details

Silylated Phosphines and Phosphoranimines,

ADA184945

Publication Date	1987
Personal Author	Neilson, R. H.; Boyd, B. A.; Dubois, D. A.; Hani, R.; Scheide, G. M.
Page Count	5
Abstract	The N-silylphosphoranimines E.G., Me3SiN=P(OCH2CF3CF3)Me2 undergo a variety of reactions including deprotonation/substitution of the P-Me groups, transilylation, and condensation with reactive phosphines. Some new 1,2-addition and oxidation reactions of the P=C systems, R2NP=CHR, R2NP(=NR) =CHR, and R2NP=CR-CH=CHR (R = SiMe3) are also reported.
Keywords	Phosphine Imines Phosphorus compounds Reprints Imines/phosphoran
Source Agency	Army Non Paid Reprints
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Corporate Authors	Texas Christian Univ., Fort Worth. Dept. of Chemistry.; Army Research Office, Research Triangle Park, NC.
Supplemental Notes	Pub. in Phosphorus and Sulfur, v30 p463-466 1987.
Document Type	Journal Article
NTIS Issue Number	198802
Contract Number	DAAG29-84-K-0147

Silylated Phosphines and Phosphoranimines,

Silylated Phosphines and Phosphoranimines,
ADA184945

Publication Date	1987
Personal Author	Neilson, R. H.; Boyd, B. A.; Dubois, D. A.; Hani, R.; Scheide, G. M.
Page Count	5
Abstract	The N-silylphosphoranimines E.G., Me3SiN=P(OCH2CF3CF3)Me2 undergo a variety of reactions including deprotonation/substitution of the P-Me groups, transilylation, and condensation with reactive phosphines. Some new 1,2-addition and oxidation reactions of the P=C systems, R2NP=CHR, R2NP(=NR) =CHR, and R2NP=CR-CH=CHR (R = SiMe3) are also reported.
Keywords	Phosphine Imines Phosphorus compounds Reprints Imines/phosphoran
Source Agency	Army Non Paid Reprints
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Corporate Authors	Texas Christian Univ., Fort Worth. Dept. of Chemistry.; Army Research Office, Research Triangle Park, NC.
Supplemental Notes	Pub. in Phosphorus and Sulfur, v30 p463-466 1987.
Document Type	Journal Article
NTIS Issue Number	198802
Contract Number	DAAG29-84-K-0147