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1,1,1,5,5,5-Hexamethyltrisiloxane: Preparation and Some Reactions.

ADA151194

Publication Date	1984
Personal Author	Seyferth, D.; Prud'Homme, C. C.; Wang, W. L.
Page Count	8
Abstract	1,1,1,5,5,5-Hexamethyltrisiloxane (I) was prepared by reaction of (Me3SiO)2Mg or of Me3 SiOH with dichlorosilane. Its selective chlorination to give mostly Me3SiOSiHClOSiMe3 and only a small amount of Me3SiOSiCl2OSiMe3 was effected by its PdCl2-catalyzed reaction with CCl4.
Keywords	Siloxanes Synthesis(Chemistry) Organic compounds Silicon compounds Hydrides Methyl radicals Silanes Chlorination Catalysis Reprints Trisiloxane/hexamethyl
Source Agency	Air Force Non Paid Reprints
NTIS Subject Category	99D - Basic & Synthetic Chemistry 99F - Physical & Theoretical Chemistry
Corporate Authors	Massachusetts Inst. of Tech., Cambridge. Dept. of Chemistry.; Air Force Office of Scientific Research, Bolling AFB, DC.
Supplemental Notes	Pub. in Jnl. of Organometallic Chemistry, v277 p203-209 1984.
Document Type	Journal Article
NTIS Issue Number	198512

1,1,1,5,5,5-Hexamethyltrisiloxane: Preparation and Some Reactions.

1,1,1,5,5,5-Hexamethyltrisiloxane: Preparation and Some Reactions.
ADA151194

Publication Date	1984
Personal Author	Seyferth, D.; Prud'Homme, C. C.; Wang, W. L.
Page Count	8
Abstract	1,1,1,5,5,5-Hexamethyltrisiloxane (I) was prepared by reaction of (Me3SiO)2Mg or of Me3 SiOH with dichlorosilane. Its selective chlorination to give mostly Me3SiOSiHClOSiMe3 and only a small amount of Me3SiOSiCl2OSiMe3 was effected by its PdCl2-catalyzed reaction with CCl4.
Keywords	Siloxanes Synthesis(Chemistry) Organic compounds Silicon compounds Hydrides Methyl radicals Silanes Chlorination Catalysis Reprints Trisiloxane/hexamethyl
Source Agency	Air Force Non Paid Reprints
NTIS Subject Category	99D - Basic & Synthetic Chemistry 99F - Physical & Theoretical Chemistry
Corporate Authors	Massachusetts Inst. of Tech., Cambridge. Dept. of Chemistry.; Air Force Office of Scientific Research, Bolling AFB, DC.
Supplemental Notes	Pub. in Jnl. of Organometallic Chemistry, v277 p203-209 1984.
Document Type	Journal Article
NTIS Issue Number	198512