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Thermal Decomposition of Molten Lithium Carbonate.

AD781765

Publication Date	1973
Personal Author	Smirnov, M. V.; Lyubimtseva, I. Y.
Page Count	10
Abstract	The equilibrium constant of the dissociation reaction of molten lithium carbonate in the temperature range 750-880C was meASURED5 A dependence of the apparent equilibrium constant on temperature was found and the change in Gibbs free energy was calculated. The dependence of the emf of the reaction system on lithium oxide concentration was measured, and it was determined that the solubility of lithium oxide in molten lithium carbonate is about 25 mole %.
Keywords	Dissociation Pyrolysis Lithium compounds Carbonates Temperature Fused salts Chemical equilibrium USSR Lithium carbonates Gibbs free energy Translations
Source Agency	Army
NTIS Subject Category	99F - Physical & Theoretical Chemistry 99D - Basic & Synthetic Chemistry
Corporate Authors	Army Foreign Science and Technology Center Charlottesville VA
Supplemental Notes	Trans. of Akademiya Nauk SSSR. Uralskii Filial, Sverdlovsk. Institut Elektrokhimii. Trudy, n16 p82-87 1970.
Document Type	Technical Report
NTIS Issue Number	197418

Thermal Decomposition of Molten Lithium Carbonate.

Thermal Decomposition of Molten Lithium Carbonate.
AD781765

Publication Date	1973
Personal Author	Smirnov, M. V.; Lyubimtseva, I. Y.
Page Count	10
Abstract	The equilibrium constant of the dissociation reaction of molten lithium carbonate in the temperature range 750-880C was meASURED5 A dependence of the apparent equilibrium constant on temperature was found and the change in Gibbs free energy was calculated. The dependence of the emf of the reaction system on lithium oxide concentration was measured, and it was determined that the solubility of lithium oxide in molten lithium carbonate is about 25 mole %.
Keywords	Dissociation Pyrolysis Lithium compounds Carbonates Temperature Fused salts Chemical equilibrium USSR Lithium carbonates Gibbs free energy Translations
Source Agency	Army
NTIS Subject Category	99F - Physical & Theoretical Chemistry 99D - Basic & Synthetic Chemistry
Corporate Authors	Army Foreign Science and Technology Center Charlottesville VA
Supplemental Notes	Trans. of Akademiya Nauk SSSR. Uralskii Filial, Sverdlovsk. Institut Elektrokhimii. Trudy, n16 p82-87 1970.
Document Type	Technical Report
NTIS Issue Number	197418