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Advanced Oxidizer Chemistry.

AD661583

Publication Date	1967
Personal Author	Solomon, I. J.
Page Count	31
Abstract	Work on the structure of dioxygenyl fluoroborate is nearing completion. Raman spectral data, and F18 tracer studies, are consistant with the O2(+) Structure. Decomposition kinetics point to an OOF intermediate in the decomposition of O2BF4. It was also found that dioxygenyl fluoborate can be prepared by two new and interesting photochemical reactions: the reaction of oxygen, fluorine and boron trifluoride and the reaction of oxygen difluoride and boron trifluoride. Tracer techniques have shown that the reaction of O2F2 with SO2 proceeds via an OOF intermediate. This work is now complete and all the O17 NMR data is presented. The OOF group was also transferred to carbon in that at least two OOF compounds are prepared by the reaction of either O2F2 or O4F2 with perfluoropropylene. (Author)
Keywords	Oxidizers Oxygen compounds Fluorine compounds Chemistry Fluoborates Molecular structure Raman spectroscopy Tracer studies Decomposition Reaction kinetics Synthesis(Chemistry) Photochemistry Nuclear magnetic resonance Halogenated hydrocarbons Sulfur compounds Oxyfluorides Dioxygenyl fluoroborate Fluorine fluoroperoxy monosulfide Fluorine fluorosulfate Oxygen fluorides Pyrosulfuryl fluoride
NTIS Subject Category	99D - Basic & Synthetic Chemistry 81H - Rocket Propellants
Corporate Authors	Iit Research Inst Chicago Ill
Document Type	Technical Report
NTIS Issue Number	196802
Contract Number	AF 49(638)-1175

Advanced Oxidizer Chemistry.

Advanced Oxidizer Chemistry.
AD661583

Publication Date	1967
Personal Author	Solomon, I. J.
Page Count	31
Abstract	Work on the structure of dioxygenyl fluoroborate is nearing completion. Raman spectral data, and F18 tracer studies, are consistant with the O2(+) Structure. Decomposition kinetics point to an OOF intermediate in the decomposition of O2BF4. It was also found that dioxygenyl fluoborate can be prepared by two new and interesting photochemical reactions: the reaction of oxygen, fluorine and boron trifluoride and the reaction of oxygen difluoride and boron trifluoride. Tracer techniques have shown that the reaction of O2F2 with SO2 proceeds via an OOF intermediate. This work is now complete and all the O17 NMR data is presented. The OOF group was also transferred to carbon in that at least two OOF compounds are prepared by the reaction of either O2F2 or O4F2 with perfluoropropylene. (Author)
Keywords	Oxidizers Oxygen compounds Fluorine compounds Chemistry Fluoborates Molecular structure Raman spectroscopy Tracer studies Decomposition Reaction kinetics Synthesis(Chemistry) Photochemistry Nuclear magnetic resonance Halogenated hydrocarbons Sulfur compounds Oxyfluorides Dioxygenyl fluoroborate Fluorine fluoroperoxy monosulfide Fluorine fluorosulfate Oxygen fluorides Pyrosulfuryl fluoride
NTIS Subject Category	99D - Basic & Synthetic Chemistry 81H - Rocket Propellants
Corporate Authors	Iit Research Inst Chicago Ill
Document Type	Technical Report
NTIS Issue Number	196802
Contract Number	AF 49(638)-1175