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Research in Fluoro-Nitro Compounds.

AD353118

Publication Date	1964
Personal Author	Baum, K.; Cavallo, J. M.; Grakauskas, V.; Mascari, M. P.
Page Count	34
Abstract	The reaction of 1-nitro-1-nitrosocyclohexane with NF2 in the presence of the BF3 complex of H3PO4 gave nitrocyclohexane and 1-nitro-1-(fluoroazoxy) cyclohexane. The uncatalyzed reaction of alkyl nitrites with NF2 gave the corresponding alcohols. 1-Chloro-1-nitrobutane was nitrosated, and the unstable product was treated with NF2 in fuming H2SO4 to give 1-chloro-1,1-bis(NF2)butane. Evidence was obtained showing that N-fluoroformamide is produced in the direct fluorination of formamide. (Author)
Keywords	Fluorine compounds Nitrogen compounds Synthesis (Chemistry) Fluorination Nuclear magnetic resonance Spectra (Infrared) Ammonium perchlorate/fluoro Nitrosation
Source Agency	Non Paid Delimited ADS
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Corporate Authors	Aerojet-General Corp., Azusa, CA.
Document Type	Technical Report
Title Note	Quarterly technical summary rept. no. 20, 1 Apr-30 Jun 64.
NTIS Issue Number	198104
Contract Number	NONR-2655(00)

Research in Fluoro-Nitro Compounds.

Research in Fluoro-Nitro Compounds.
AD353118

Publication Date	1964
Personal Author	Baum, K.; Cavallo, J. M.; Grakauskas, V.; Mascari, M. P.
Page Count	34
Abstract	The reaction of 1-nitro-1-nitrosocyclohexane with NF2 in the presence of the BF3 complex of H3PO4 gave nitrocyclohexane and 1-nitro-1-(fluoroazoxy) cyclohexane. The uncatalyzed reaction of alkyl nitrites with NF2 gave the corresponding alcohols. 1-Chloro-1-nitrobutane was nitrosated, and the unstable product was treated with NF2 in fuming H2SO4 to give 1-chloro-1,1-bis(NF2)butane. Evidence was obtained showing that N-fluoroformamide is produced in the direct fluorination of formamide. (Author)
Keywords	Fluorine compounds Nitrogen compounds Synthesis (Chemistry) Fluorination Nuclear magnetic resonance Spectra (Infrared) Ammonium perchlorate/fluoro Nitrosation
Source Agency	Non Paid Delimited ADS
NTIS Subject Category	99D - Basic & Synthetic Chemistry
Corporate Authors	Aerojet-General Corp., Azusa, CA.
Document Type	Technical Report
Title Note	Quarterly technical summary rept. no. 20, 1 Apr-30 Jun 64.
NTIS Issue Number	198104
Contract Number	NONR-2655(00)