National Technical Reports Library

The National Technical Information Service acquires, indexes, abstracts, and archives the largest collection of U.S. government-sponsored technical reports in existence. The NTRL offers online, free and open access to these authenticated government technical reports. Technical reports and documents in its repository may be available online for free either from the issuing federal agency, the U.S. Government Publishing Office’s Federal Digital System website, or through search engines.

Details

Research on Chemistry of O3F2 and O2F2.

AD296867

Publication Date	1963
Personal Author	Solomon, I. J.
Page Count	13
Abstract	Previous studies indicate that certain members of the oxygen-fluorine system of compounds have excellent potential as oxidizing and fluorinating agents. Although work has been carried out on the synthesis, structure, physical properties, and thermal decomposition of O3F2 and O2F2, information on the reaction chemistry is seriously lacking. Therefore, the main objective of this program is to elucidate the reactions of O3F2 and O2F2 with inorganic compounds. At the time of the last report there was some concern about the validity of the procedure used for the analysis of the reaction products. The method has now been validated. Study of the chemistry of the interesting compound, O2BF4, has continued. A new compound which has tentatively been assigned the formula O2PF6, has been prepared and is being characterized further.
Keywords	Oxidizers Oxygen compounds Fluorides Chemical properties Chemical reactions Inorganic compounds Decomposition Stability Alkaline earth metals Magnesium Phosphorus Infrared spectroscopy Mass spectrum Paramagnetic resonance Absorption spectrum Oxygen Fluorine Fluorination Boron compounds Oxygen fluorides Oxygen boron fluoride Oxygen phosphorus fluoride
Corporate Authors	Iit Research Inst., Chicago, Ill.
Document Type	Technical Report
Title Note	Technical summary rept. no. 2, 1 Oct-31 Dec 62.
NTIS Issue Number	196401
Contract Number	AF49 638 1175

Research on Chemistry of O3F2 and O2F2.

Research on Chemistry of O3F2 and O2F2.
AD296867

Publication Date	1963
Personal Author	Solomon, I. J.
Page Count	13
Abstract	Previous studies indicate that certain members of the oxygen-fluorine system of compounds have excellent potential as oxidizing and fluorinating agents. Although work has been carried out on the synthesis, structure, physical properties, and thermal decomposition of O3F2 and O2F2, information on the reaction chemistry is seriously lacking. Therefore, the main objective of this program is to elucidate the reactions of O3F2 and O2F2 with inorganic compounds. At the time of the last report there was some concern about the validity of the procedure used for the analysis of the reaction products. The method has now been validated. Study of the chemistry of the interesting compound, O2BF4, has continued. A new compound which has tentatively been assigned the formula O2PF6, has been prepared and is being characterized further.
Keywords	Oxidizers Oxygen compounds Fluorides Chemical properties Chemical reactions Inorganic compounds Decomposition Stability Alkaline earth metals Magnesium Phosphorus Infrared spectroscopy Mass spectrum Paramagnetic resonance Absorption spectrum Oxygen Fluorine Fluorination Boron compounds Oxygen fluorides Oxygen boron fluoride Oxygen phosphorus fluoride
Corporate Authors	Iit Research Inst., Chicago, Ill.
Document Type	Technical Report
Title Note	Technical summary rept. no. 2, 1 Oct-31 Dec 62.
NTIS Issue Number	196401
Contract Number	AF49 638 1175